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化学 大学生・専門学校生・社会人

はじめまして。 問2.3がわからなくてとても困っています。 もしよろしければ教えていただきたいです。 よろしくお願いします。

<問題> 1) 安息香酸、クロロフェノール、アントラニル酸メチルのpK』 をPubChem で調査せよ。 2) 二つの化学種が平衡状態にあるとき、 Gibbs 自由エネルギー差はAG =-RT In K で表 される。 ここでKは平衡定数 (ある化学種に占めるもう一方に化学種の割合) である。 メチルシクロヘキサンのメチル基がアキシアルを占める立体配座とエクアトリアルを 占める立体配座の標準状態における存在比を求めよ。 計算実験で得られた立体配座異 性体のエネルギーの差を Gibbs 自由エネルギー差の近似値として用いてよい。 なお、In (エルエヌ) は自然対数を指しInx = yならばey=x (左辺はexp (y) と書くこともある) である。 気体定数は R ≒ 8.31 JK-1 mol-1 を用いよ (Bruice 有機化学、 5.7 参照)。 3) メタン、エチレン、アセチレンの分子軌道を量子化学計算の一種であるハートリー・ フォック法により計算せよ。 Engine: Gamess, Calculation: Molecular Orbitals, Theory: RHF, Basis Set: Minimal:STO-3G を指定せよ。 各化合物はそれぞれいくつの 分子軌道をもつか。 上記のうち、 多重結合を有する化合物について、 全ての軌道を 図示し占有数(Occupancy) を示せ。 また、 それぞれの化合物の結合角(∠HCH やく HCC) はおよそ何度か。 これまでに学習した軌道の混成状態についての知識と比較せ よ。

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生物 大学生・専門学校生・社会人

至急お願いいたします🚨 生物の質問です。 ミトコンドリアの経路についての説明だと思うのですが、電子オーバーフローモデルと電子分布モデルの違いを教えていただきたいです。 また、どういう仕組みなのか、何故このように電子が流れるのかも教えていただきたいです。 UQ poolはユ... 続きを読む

(A) Electron overflow model (considered out-of-date) Alt UQ pool Alternative oxidase inactive. Alt No alternative pathway activity Cytochrome pathway unsaturated Cyt (B) Electron distribution model (reflects current thinking) UQ pool Cyt Alternative pathway active Cytochrome pathway saturated Alt Alternative oxidase active Alt UQ pool Cyt Cyt Figure 14.33 Two models for regulation of electron flow through the alternative oxidase. (A) In the electron overflow model, no appreciable electron transfer through the alternative pathway takes place until electron flow through the cytochrome pathway is at or near satu- ration. This could result from the effects of respirato- ry control, if the rate of mitochondrial ATP produc- tion exceeds its rate of utilization in the cytosol, or from some externally imposed stress, such as low temperature. Under such circumstances, the UQ pool becomes sufficiently reduced to allow electrons to flow through the alternative oxidase, the latter re- quiring that the UQ pool be 40% to 60% reduced to attain significant activity. (B) In the electron distribu- tion model, the alternative and cytochrome path- ways both show significant activity at low levels of UQ pool reduction, and electrons are distributed be- tween the two pathways on the basis of the relative activities of each pathway. The activity of the alter- native oxidase under these circumstances is thought to be regulated by the action of a-keto acids and by reduction/oxidation of the intermolecular disulfide bond, as well as by additional regulatory mecha- nisms not yet characterized.

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英語 高校生

並べ替えの問題がわかりません🥲教えてくださいお願いします🙇‍♀️

rmativ nt Each of us carries just over 20,000 genes that encode everything from the keratin in our hair down to the muscle fibers in our toes. It's no great (1) (own / came / where / from / our / mystery / genes): our parents bequeathed them to us. And our parents, in turn, got their s genes from their parents. But where along that genealogical line did each of those 20,000 protein-coding genes get its start? That question has hung over the science of genetics (2) (ago / dawn / century / since / a / ever / its). "It's a basic question of life: how evolution generates 1 novelty," said Diethard Tautz of the Max Planck Institute for 10 Evolutionary Biology in Plön, Germany. New studies are now bringing the answer into focus. Some of our genes are immensely old, perhaps (3) (to / way / back / dating / all the / the) earliest chapters of life on earth. But a surprising number of genes emerged more recently. many in just the past few million years. The youngest evolved after our 15 own species broke off from our cousins, the apes. Scientists (4) (being / finding / into / are / genes / come / new) at an unexpectedly fast clip. And once they evolve, they can quickly take on essential functions. Investigating how new genes (5) (understand / help / become / scientists / important / may / so) the role they may play in diseases like cancer. [1] Read the passage and rearrange the seven words in (1) - (5) in the correct order. Then choose from 1-4 the option that contains the third and fifth words. (1) 13rd: our (2) (3) (4) (5) 5th: genes 3rd: ago 5th: since 3rd: back 5th: the 2 3rd: where 5th: came 2 3rd: its 5th: ever 23rd: the 5th: back 2 3rd: genes 5th: into 1 3rd: genes 5th: being 1 3rd: may 5th: scientists 3 3rd: scientists 5th: understand 3 3rd: genes 5th: from 3 3rd: its 5th: a 3 3rd: way 5th: back 3 3rd: finding 5th: genes 23rd: important 5th: help 43rd: help 3rd: own 5th: came 3rd: came 5th: dawn 43rd: the 5th: the 4 3rd: new 5th: come 5th: understand may may understand thep (早稲田大) wystery. ne TOL Recome Sc

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英語 高校生

全文訳お願いします!

4 20 科学 420 words Chapter 1 The recipe for making any creature is written in its DNA. So last year, when 1-1 geneticists* published the near-complete DNA sequence of the long-extinct woolly mammoth, there was much speculation about whether we could bring this giant creature back to life. 5 東京理科大学 Creating a living, breathing creature from a genome* sequence that exists only in a computer's memory is not possible right now. But someone someday is sure to try it, predicts Stephan Schuster, a molecular biologist at Pennsylvania State University and a driving force behind the mammoth genome project. So besides the mammoth, what other extinct beasts might we bring back to life? Well, 12 10 it is only going to be possible with creatures for which we can recover a complete genome Without one, there is no chance. And usually when a creature dies, the (1) - DNA in any flesh left untouched is soon destroyed as it is attacked by sunshine and bacteria. sequence. There are, however, some circumstances in which DNA can be preserved. If your 15 specimen froze to death in an icy wasteland such as Siberia, or died in a dark cave or a really dry region, for instance, then the probability of finding some intact stretches of DNA is much higher. Even in ideal conditions, though, no genetic information is likely to survive more than a million years. - so dinosaurs are out and only much younger remains are likely to yield good-quality DNA. "It's really only worth studying specimens that are less than 100,000 years old," says Schuster. The genomes of several extinct species besides the mammoth are already being sequenced, but turning these into living creatures will not be easy. "It's hard to say that something will never ever be possible," says Svante Pääbo of the Max Planck Institute 25 for Evolutionary Anthropology in Germany, "but it would require technologies so far removed from what we currently have that I cannot imagine how it would be done." But then (3) 50 years ago, who would have believed we would now be able to read the instructions for making humans, fix inherited diseases, clone mammals and be close to creating artificial life? Assuming that we will develop the necessary technology, we have 30 selected ten extinct creatures that might one day be resurrected. Our choice is based not just on practicality, but also on each animal's "charisma" - just how exciting the prospect of resurrecting these animals is. 1-3

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英語 高校生

わからないです

[5 次の英文を読み。 以下の設問に答えよ。 (配点 60点 xtenSiVe を て of your Your dog's ability to learn new tricks may be less a product 7aining (han of ther underlying *genetics ch as aral traits such Among 101 dog *breeds, scientists found that certain behavioral 0 genetically Sirmila 00Gr or Aproasion were more HMI GR PE時昌汗EE 2 S dog behaviors breeds、 While past studies have looked into the genetic foundations of ・the 2ceeg7zzgs の 7@ for certain breeds、thiS research published October 1 in *the /ァの preeds and find a な is the first to investigate a wide diversity of netic signal behavioral aly。 everyone knows that different dogs have 中作erent : の 7ashington in ~ says Noah Snyder-Mackler, a geneticist at the University of Washing Ks の Sa *canines have lived de "But we didnt know how much or why.” Humans and *canine at least 15.000 years. But only within the last 300 years or so have produced Yarieties such as Chihuahuas and Great Danes. Snyder-Mackler and his colleagues considered how 101 dog breeds behave while searching for genetic similarities among breeds sharing certain personality graits. Data came from two dog genotype databases and from C-BARQ, a survey 好at asks owners to rank their pure-bred dog's "propensity for certain behaviors, hike chasing or aggressiveness toward strangers. As a result the study didnt have genetic and behavioral data from the same canine individuals, which could help 岳ghjjght rare genetic varjants that may be nonetheless important to diversity im pehavjors. “Tjeyre not perfect sources of data” says Clive Wynne, an animal behaviorist at Arizona State Unjversity jn Tempe, who was not involved in the study. “But allowed fhem to Jook at ots and lots of dogs.” Using daa from over 14000 dogs described in C-BARQ, the researchers gave each breed a score for 14 different behaviors, and then searched for overall genetic simlarifies among breeds that had similar Scores. For traits such as aggression foward sfrangers, franability and chasing, the researchers found that genes ルー Yo

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