大学、無機化学、配位化学です (1)について質問です 最大モル吸光係数が大きい順 →光の吸収が強い順 →dd遷移で結晶場大きい順 と考え、分光化学系列から(い)、(あ)の順になるのはわかるのですが、(う)のedtaの取り扱いがわからず、(う)がどこに行くのかわかりません。わ... 続きを読む

ことが知られている。 1) d-d 遷移の最大モル吸光係数 Emax が大きいと考えられる順に以下の金属錯体の記号 (あ)~(う) を並べよ。 (あ) [Cr(OH)] 3+ (い)[Cr(NH3)5(OH)]+ (う) [Cr(edta)] (edta: エチレンジアミンテトラアセタト) 2) 一般に四面体錯体のd-d遷移のEmax は八面体錯体のものよりも大きい。 その理由を25字以内で答えよ。

【複素積分】(1)の解き方を教えていただけないでしょうか。

正の方向のジョルダン曲線 (Jordan curve) C の上と内部で複素関数f(z) が正則である とき、 曲線Cの内部の任意の点で、 f(20) = が成立する。 これをコーシーの積分公式という｡ f'(zo) 問題 2.3 次の複素積分の値を求めよ。 ただし、 閉曲線は正の方向に1周するものとする。 3 2 (1) Long [(z − 1)² + z ²³ ; − (2 ² ¡js) dz dz (2) √₁41-2 (3) Sal= dz (4) √121-3 |z|=3 (-2)(z +4) f" (20) 1 f(z) 2mi JcZ0 f(n) (zo) 22-9 dz コーシーの微積分公式 (Cauchy's differentiation formula) 正の方向のジョルダン曲線Cの上と内部で複素関数f(z) が正則であるとき、 任意の階 数の導関数はこの領域で正則であり、 次式で与えられる。 = = dz 1 f(z) 2πi Jc (z-zo)² n! maile dz 2! 27i Sc (z=-²20) ³ f(z) (20)n+1 (5) dz (6) (7) (8)

このプリントの日本語訳を教えてください

未習長文D インフォメーションリスト |adopt medicine to start to deal with or think about something ina particular wav 1. a substance used for treating an illness, especially a liquid you drink the treatment and study of illnesses and injuries 2. to depend on someone to provide help, advice, etc. to think that you are better than someone else, for example because you are more sucessful, or of a higher social lass than they are fair and sensible look to look down on reasonable can/could afford people were better off using It would be better for people to use traditional traditional medicine rather than medicine rather than having no medicine. no medicine at all. establish to have enough money to buy or pay for something to start a company, organization, system, etc. that is intended to exist or continue for a long time 1.(n) the work of a doctor or lawyer, or the place where they work 2.(v) to use a particular method or custom the act of starting an organization, relationship, or system the process or fact of being received as adequate, valid, or suitable practice establishment acceptance a small creature such as a fly or ant, that has six legs, and sometimes wings anything that is living, such as an animal, fish, or insect, but not a plant a plant like a small onion, used in cooking to give a strong insect creature garlic taste bacteria very small living things, some of which causes illness or disease a chemical substance found in your blood. cholesterol in your blood may cause heart disease. to absorb something into the body, for example by breathing or swallowing a scientific test done to find out how something reacts under certain conditions, or to find out if a particular idea is true (v) to make something less dense or numerous look at something again closely if someone has a stroke, an artery (tube carrying blood) in their brain suddenly bursts or becomes blocked, so that they may not real or not made of natural things but made to be like something that is real or natural a substance used in chemistary or produced by achemical cholesterol Too much take in experiment thin take a second look at stroke die or be unable to use some muscles artificial chemical process to help to make something happen to help to make something happen Contribute think highly of o place Migh value on

定積分の計算で∫∂/∂x～～～dxというような形の式があるのですが、この場合 ∂/∂xがあるので先に～～～の部分をxで微分してからxで定積分するということでしょうか。

This assumption may be valid because the air column being considered is deeper than the nocturnal turbulent boundary layer. QE is the latent heat flux which is released into the air column with the phase change of water vapor. When there is no phase change of water vapor, QE=0. QR is the heat flux of the long wave radiation and defined by QR=pC * a 0z where (30 /a1), s the warming rate of air due to convergence of long wave radiation, L t(z) and L(2) are the upward and downward long wave radiation at a height of z respectively. Among several kinds of calculation methods for long wave radiation (Stephens, 1984), formulae

多様体の接空間に関する基底定理の証明です。g(q)=∫〜と定義した関数を微積分学の基本定理を用いながら変形してg(q)=g(0)+∑gᵢuⁱと導出するのですが、これがうまくいきません。 自分は、g(q)の式をまず両辺tで微分して、次に両辺uⁱで積分して、最後に両辺tで積分... 続きを読む

12. Theorem.If{ = (x', , x") is a coordinate system in M at p, then its coordinate vectors d, lp, …… 0,l, forma basis for the tangent space T,(M); and D= E(x) 。 i=1 for all ve T(M). Proof. By the preceding remarks we can work solely on the coordinate neighborhood of G. Since u(c) = Othere is no loss of generality in assuming ど(p) = 0eR". Shrinking W if necessary gives E(W) = {qe R":|q| < } for some 8. Ifg is a smooth function on E(W) then for each 1 <isndefine og (tq) dt du g(9) = for all qe {(W). It follows using the fundamental theorem of calculus that g= g(0) + E&,u' on (W). Thus if fe &(M), setting g = f。' yields f= f(P) + Ex on U. Applying d/ax' gives f(p) = (f /0x)(P). Thus applying the tangent vector e to the formula gives (f) = 0+ E(x'(p) + E Ap)u(x) = E(Px). ず ax Since this holds for all f e &(M), the tangent vectors v and Z Ux') d,l, are equal. It remains to show that the coordinate vectors are linearly independent. But if ) a, o.l, = 0, then application to x' yields dxi 0=24 (P) = 2q d」= 4. In particular the (vector space) dimension of T,(M) is the same as the dimension of M.