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化学 大学生・専門学校生・社会人

はじめまして。 問2.3がわからなくてとても困っています。 もしよろしければ教えていただきたいです。 よろしくお願いします。

<問題> 1) 安息香酸、クロロフェノール、アントラニル酸メチルのpK』 をPubChem で調査せよ。 2) 二つの化学種が平衡状態にあるとき、 Gibbs 自由エネルギー差はAG =-RT In K で表 される。 ここでKは平衡定数 (ある化学種に占めるもう一方に化学種の割合) である。 メチルシクロヘキサンのメチル基がアキシアルを占める立体配座とエクアトリアルを 占める立体配座の標準状態における存在比を求めよ。 計算実験で得られた立体配座異 性体のエネルギーの差を Gibbs 自由エネルギー差の近似値として用いてよい。 なお、In (エルエヌ) は自然対数を指しInx = yならばey=x (左辺はexp (y) と書くこともある) である。 気体定数は R ≒ 8.31 JK-1 mol-1 を用いよ (Bruice 有機化学、 5.7 参照)。 3) メタン、エチレン、アセチレンの分子軌道を量子化学計算の一種であるハートリー・ フォック法により計算せよ。 Engine: Gamess, Calculation: Molecular Orbitals, Theory: RHF, Basis Set: Minimal:STO-3G を指定せよ。 各化合物はそれぞれいくつの 分子軌道をもつか。 上記のうち、 多重結合を有する化合物について、 全ての軌道を 図示し占有数(Occupancy) を示せ。 また、 それぞれの化合物の結合角(∠HCH やく HCC) はおよそ何度か。 これまでに学習した軌道の混成状態についての知識と比較せ よ。

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TOEIC・英語 大学生・専門学校生・社会人

このプリントの日本語訳を教えてください

未習長文D インフォメーションリスト |adopt medicine to start to deal with or think about something ina particular wav 1. a substance used for treating an illness, especially a liquid you drink the treatment and study of illnesses and injuries 2. to depend on someone to provide help, advice, etc. to think that you are better than someone else, for example because you are more sucessful, or of a higher social lass than they are fair and sensible look to look down on reasonable can/could afford people were better off using It would be better for people to use traditional traditional medicine rather than medicine rather than having no medicine. no medicine at all. establish to have enough money to buy or pay for something to start a company, organization, system, etc. that is intended to exist or continue for a long time 1.(n) the work of a doctor or lawyer, or the place where they work 2.(v) to use a particular method or custom the act of starting an organization, relationship, or system the process or fact of being received as adequate, valid, or suitable practice establishment acceptance a small creature such as a fly or ant, that has six legs, and sometimes wings anything that is living, such as an animal, fish, or insect, but not a plant a plant like a small onion, used in cooking to give a strong insect creature garlic taste bacteria very small living things, some of which causes illness or disease a chemical substance found in your blood. cholesterol in your blood may cause heart disease. to absorb something into the body, for example by breathing or swallowing a scientific test done to find out how something reacts under certain conditions, or to find out if a particular idea is true (v) to make something less dense or numerous look at something again closely if someone has a stroke, an artery (tube carrying blood) in their brain suddenly bursts or becomes blocked, so that they may not real or not made of natural things but made to be like something that is real or natural a substance used in chemistary or produced by achemical cholesterol Too much take in experiment thin take a second look at stroke die or be unable to use some muscles artificial chemical process to help to make something happen to help to make something happen Contribute think highly of o place Migh value on

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